Table 1: Vibrational phase and Raman tensor form of the Raman spectrum of polyethylene [32,33,42,43].

Raman shift /cm-1 Mode Phase Raman tensor
1063 νas (C-C) Trans chain B2g + B3g
1080 ν (C-C) Amorphous -
1130 νs (C-C) Trans chain Ag + B1g
1298 νt (C-C) Crystalline B2g + B3g
1313 νt (C-C) Amorphous -
1418 δ (CH2)
ω (CH2)
Crystalline
(orthorhombic)
Ag
1440 δ (CH2) Amorphous trans
(intermediate)
Ag + B1g
1460 δ (CH2) Amorphous Ag + B1g

ν: stretching, νas: anti-symmetric stretching, νs: symmetric stretching, νt: twisting, δ: bending, ω: wagging